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Aurelian coin restitutor orbis1/16/2024 ![]() ![]() IMP C L DOM AVRELIANVS PF AVG, laureate, cuirassed bust left. G&M 160, 2456 var (obv legend).Īurelian AE Denarius or As. IMP AVRELIANVS P AVG, radiate, cuirassed bust right / IOVI CONSER, Emperor standing right, holding sceptre, receiving globe from Jupiter, standing left, holding sceptre. Goebl 372a Estiot 165 Hunter 40 (this coin).Īurelian, AE Antoninianus. RESTITVTOR ORIENTIS, Sol, holding whip and raising right hand, walking left between two seated captives. IMP C AVRELIANVS AVG, radiate, cuirassed bust right. Ref: Goebl 367b5 Sear 11634 Not in RIC.Īurelian AV Binio. IMP C AVRELIANVS AVG, radiate, cuirassed bust right / VIRTVS ILLVRICI, Mars walking right with spear and shield, captive at foot. RIC - Cohen - Goebl 244a O (this coin).Īurelian, Antioch, AE Antoninianus. IMP AVRELIANVS P AVG, laureate, draped, cuirassed bust left, holding spear and shield decorated with Victory between two bound captives / ORIENS AVG, Sol, radiate, naked except for chlamys over shoulder, walking left, holding whip and raising right hand. Goebl 222c5 Siscia.Īurelian, AR denarius from aureus dies, 21mm, 2,99g. IMP C AVRELIANVS AVG, radiate, cuirassed bust right / ORIENS AVG, Sol standing left, holding globe, right hand raised, captive at foot left. Goebl 222c2 var (mintmark) RIC -.Īurelian, Siscia, Aurelianus. IMP C AVRELIANVS AVG, radiate, cuirassed bust right / ORIENS AVG, Sol standing front, looking left, holding globe and raising right hand captive at foot left. Goebl 213-2c RIC V-1, 218 Siscia var (bust type).Īurelian, AE antoninianus. IMP AVRELIANVS AVG, radiate, cuirassed bust left, holding spear and shield / CONCORDIA MILITVM, Emperor standing right, clasping hands with Concordia, standing left. Goebl 166A Sear 11632 RIC -.Īurelian, billon antoninianus, Siscia. VIRTVS AVG, Emperor on horseback, galloping right, spearing enemy on ground. ![]() Goebl 62b3 Milan Horvath 72a Belfort 213 in Ann. IMP AVRELIANVS AVG, radiate, cuirassed bust right (large lettering) / VIRTVS MILITVM, Emperor left, facing right, holding spear and globe receiving Victory from soldier opposite, facing left, holding transverse spear. IMP AVRELIANVS AVG, radiate, cuirassed bust right / VIRTVS MILITVM, Emperor standing right, holding spear and globe, receiving Victory from soldier, standing left, holding transverse spear. Sear 11481 Goebl 13 RIC - Cohen -.Īurelian, AE antoninianus. IMP C D AVRELIANVS AVG, laureate, draped, cuirassed bust right / MARTI PACIFERO, Mars standing left, holding branch and spear. Not in RIC for Aurelian from any mint BN 1150 (same reverse die?).Īurelian, AV Aureus, Milan. IMP AVRELIANVS AVG, radiate, cuirassed bust right / VICTORIA AET, Victory standing left on globe set on exergual line, wreath upward in right hand, palm in left over shoulder. Finally, RIC does not always distinguish between dots in mintmarks, so the mintmark XXI dot S is not necessarily a var of XXIS.Īurelian, AE Antoninianus, Late 271 AD, Cyzicus. In addition: Serdica: bust images greatly resemble those of Claudius II. More "normal" (or thick) necks and large cuirass: usually Milan. To aid identification: Long neck: Sisica Wide upper body and very large cuirass: Siscia. NOTE: Many ORIENS types of Milan and Siscia have identical markings, reverses, legends and mintmarks. Many coins still have traces of what sellers call "silvering" on them, however, metallurgical tests show that, in most cases, the "silver" is actually tin.īrowse the Aurelian page with thumbnail images. Aurelian, Roman Imperial Coins reference at īrowsing Roman Imperial Coins of Aurelian ![]()
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Recboot1/16/2024 ![]() ![]() You can put your iPhone in Recovery Mode by clicking on Enter Recovery Mode.After the device is recognized, you have two options.The window would show the status as no device connected.Extract and run the RecBoot file you have downloaded.You can download the macOS version, that is, RecBoot 2.2 from here. That cannot be done by iTunes or any other Apple software. The reason is that by using RecBoot, you can retrieve your device to normalcy without losing data. This saves a lot of time.īut there is another reason why so many users opt for iOS Recovery software like RecBoot, instead of using iTunes. Then, run the software to enter/exit recovery mode with a single mouse click. ![]() NET framework.Īll you have to do is get RecBoot for Mac and Windows from our links. RecBoot 1.3 and RecBoot 2.2 for Windows and Mac, respectively, don’t even need installation of supportive software like Java or. RecBoot is a very simple software which is available free to download online. Additionally, there are other modes your iPhone can get into, like Boot Loop and DFU Mode. Sometimes a failed Jailbreak can also push your iPhone into Recovery Mode Loop. It makes your device continuously boot into recovery mode even when you want it to boot in normal mode. Recovery Mode Loop is a condition caused by software failures, usually from faulty iTunes software or incomplete iOS Update installation. In recovery mode, your iPhone screen shows iTunes or computer logo on a black background. In Addition, this mode uses iBoot to restore your iPhone as well. It is put in place by Apple to help your iPhone to upgrade to a new version of iOS. Recovery Mode is a failsafe in iBoot, the iOS booting system. Either their iPhone is booting into Recovery Mode or their home button is broken or both.Ĥ. Most people who download RecBoot use it as a quick fix to troubleshoot their iDevice. RecBoot is a free software which allows anyone to put their iPhone, iPad or iPod touch in and out of Recovery Mode with just a click of the mouse directly from their Mac or Windows PC. Want to download RecBoot? Then you are either in a hurry or in serious trouble with your iOS device. ![]()
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Java for mac 10.9 51/16/2024 ![]() This seems to be the same/similar Java/JRE error that was causing problems with ZD7.2.5. Zclient.IO_ERROR: Remote host closed connection during handshake. When we try to add a new email account of type Zimbra, we get the following error message: ![]() She took her laptop to the Apple Store, where they removed old copies of ZD and also old copies of JRE. We thought ZD 7.2.7 would fix the problem but it has not. This is my first time posting here, so maybe I don't properly understand how it works. Yes, I've clicked the blue "+ New" button in upper right. But when I tag it as a question, shows me old questions and doesn't seem to permit me to actually enter my new question. But no luck.This is intended as a Question, not a Discussion. So, all in all if anyone can help me regarding this opencv error then it would be a great help. dll path seems to be a workaround, if you can suggest any better way, then it s better. ![]() ![]() So, i tried searching 32 bit JDK for Mac, but there is no such JDK.Īpart from it, directly giving the. ![]() īut this also doesnt work as when putting -d32 in the arguments tab, it says 32bit not supported by JVM. I tried searching for libOpenCV.jnilib/.dylib but couldnt find them as OpenCV is not installed in the Mac.Įven if we are able to install it using cmake/macports i couldnt find any build folder with the required. So, after a lot of googling i found out that - System.loadLibrary("Complete Path to opencv.dll") works for Windows.īut still it doesnt work for Mac as there are no precompiled. While using OpenCV i got NoClassDefFoundError so I gave - System.loadLibrary(Core.NATIVE_LIBRARY_NAME) Īfter which it started giving - Exception in thread "main" : no opencv_java249 in So, I am trying to use OpenCV with Eclipse in Mac 10.9.5 in a Maven project for software automation testing. ![]()
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Zotero vs endnote 2018 reddit1/16/2024 ![]() ![]() The infographic below demonstrates how automated citation recommendation tools can be implemented in an accelerated research process, omitting several phases of a more valid/rigorous/systematic/reliable process. ![]() According to a recent article published in Research Evaluation, automated citation recommendation tools replace a crucial stage of the research process: the literature searching and critical appraisal of the literature, and they facilitate a rather thoughtless way of citing, requiring little scrutiny from the authors. In contrast, automated citation recommendation tools find relevant literature based on the input of a piece of text, such as a statement or paragraph, and then retrieve relevant citations to back the claims made by the author. ![]() Image: Reflection Building DistortionĬollectively, literature mapping tools, databases, and search engines help researchers at the literature search phase and act as paper recommendation tools they use the input of search terms or seed paper(s) to find relevant results search engines and databases rely on the user inputting search terms, whereas literature mapping tools rely on the user inputting a seed paper to generate relevant papers using a similarity algorithm based on bibliographic coupling and co-citations. While promising to accelerate the writing process, citation recommendation tools come with major drawbacks, prompting questioning of what exactly are their benefits and perhaps unintended implications of using. More recently, citation recommendation tools have been developed, such as Citeomatic and its successor Specter. In order to use these literature mapping tools, one must first have a seed paper to plug into the tool which then finds other relevant papers based on algorithms of co-citations and bibliographic coupling. This was followed by the emergence of literature mapping tools to help with literature searching, such as LitMaps, Citation Gecko, Inciteful, and Connected Papers (see this blog post for an in-depth review of such tools). As a result, citation management tools have been developed, such as Mendeley, Zotero, and EndNote. One daunting task all researchers face is finding, managing and tracking citations for their manuscripts. However, faster does not always mean smarter. In an increasingly competitive academic environment, researchers are understandably keen to find smarter, faster ways to complete their projects. Remember that you can move your references between programs, so if you don't like one program you can always switch.Rachel Miles summarizes a recently published journal article that cautions researchers on the use of automated citation recommendation tools, which are designed to help academic authors cite literature in the writing phase of their research project while potentially skipping crucial steps of searching, reviewing, and appraising literature. View our FAQ on which citation managers work best for systematic reviews for more information. Both allow ingestion of large result files from multiple databases and provide deduplication options. Systematic Reviews: HSL librarians prefer EndNote Desktop or Sciwheel for systematic reviews.If you are just forming a team, look at the sharing features in Sciwheel and Zotero. Working with a team: If you are joining an established team that has already chosen a particular reference management tool, it is a good idea to learn to use that tool.EndNote will search for available full-text when you are on campus and this is a very quick way to download and organize the full-text of multiple recent references. Storing PDFs: EndNote, Sciwheel, or Zotero allow you to integrate downloaded PDFs with your reference database.This feature is coming soon from Sciwheel. ![]()
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Kitchen designer jobs virginia1/16/2024 ![]() ![]() While there is a fairly large ‘grey market’ of unlicensed companies, there are those that have membership in a reputable association and/or are accredited by a professional organization. These are the builders that have specialized credentials, licensing and experience to perform renovation services in specific municipalities. Perhaps the most important or visible professionals in the renovation industry are renovation contractors or skilled trades. He is said to have become wealthy himself by buying villas at a low price, adding spas and his newly invented hypocaust, and reselling them at higher prices. The hypocaust is an underfloor heating system that was used throughout the Roman Empire in villas of the wealthy. is said by the writer Vitruvius (in his famous book De architectura) to have invented the hypocaust. One example is Sergius Orata, who in the 1st century B.C. Professional home improvement is ancient and goes back to the beginning of recorded civilization. The average cost per project is $3,000 in the United States and $11,000–15,000 in Canada. Home or residential renovation is an almost $300 billion industry in the United States, and a $48 billion industry in Canada. Home improvement industry Screws and bolts in OBI home improvement store in Poland Backup generators for providing power during power outages.Bomb shelters especially during the 1950s as protection from nuclear war.Storm cellars as protection from tornadoes and hurricanes.Fire sprinkler systems to protect homes from fires.Renewable energy with biomass pellet stoves, wood-burning stoves, solar panels, wind turbines, programmable thermostats, and geothermal exchange heat pumps (see autonomous building).Įmergency preparedness safety measures such as:.Energy-efficient thermal insulation, replacement windows, and lighting.Homeowners may reduce utility costs with: Such a new unit of construction is called an "add-on". Extending one's house with rooms added to the side of one's home or, sometimes, extra levels to the original roof.Turning marginal areas into livable spaces such as turning basements into recrooms, home theaters, or home offices – or attics into spare bedrooms.Plumbing, home interior and exterior works.Repairing plumbing and electrical systems.Concrete and masonry repairs to the foundation and chimney.Replacement or new construction windows.Soundproofing rooms, especially bedrooms and baths.Increasing the capacity of plumbing and electrical systems.Upgrading rooms with luxuries, such as adding gourmet features to a kitchen or a hot tub spa to a bathroom.Upgrading heating, ventilation and air conditioning systems ( HVAC).Home improvement projects generally have one or more of the following goals: Comfort It also encompasses maintenance, repair, and general servicing tasks. While "home improvement" often refers to building projects that alter the structure of an existing home, it can also include improvements to lawns, gardens, and outdoor structures, such as gazebos and garages. ![]() Home improvement projects can be carried out for a number of different reasons personal preference and comfort, maintenance or repair work, making a home bigger by adding rooms/spaces, as a means of saving energy, or to improve safety. garden work or garage maintenance/additions). Home improvement can consist of projects that upgrade an existing home interior (such as electrical and plumbing), exterior (masonry, concrete, siding, roofing) or other improvements to the property (i.e. The concept of home improvement, home renovation, or remodeling is the process of renovating or making additions to one's home. ( Learn how and when to remove this template message) To comply with Wikipedia's lead section guidelines, please consider modifying the lead to provide an accessible overview of the article's key points in such a way that it can stand on its own as a concise version of the article. ![]() This article's lead section may not adequately summarize its contents. ![]()
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Myst 4 bookshelf puzzle1/15/2024 ![]() ![]() I don't mind fucking complaining about Myst, or any of the problems I had with the sequels but for fuck's sake complain about the game's actual faults, not one you just pulled out of your ass: complaining about puzzles being illogical in a game when most of the shit is predictable, mechanical and with so many solutions spoon-fed to you just fucking baffles me. Or if you had to play it not in your native language and so didn't understand that first clue. Or that if you were hard of hearing, then you were fucking screwed on the Age connected to the spaceship, or that the maze was far too slow to navigate if you'd not done Ages in the right order and missed a clue (though that wasn't necessary to complete it), and was slow even when you know what you were doing. I mean, if you were to complain about the organ puzzle in the space ship being a pain in the ass because the input tended to slip a note if you weren't careful (at least, in the original version)l, that's one thing. The books in the libary - the ones you can read, anyway - do the rest. Doing that and exploring behind the bookshelf in the library, accessed by one of the other paintings, let's you in on the Tower of Clues that basically hand-holds you through getting into most of the other Ages.Clicking on it has an effect, just like every other painting in there seems to have, and its really obvious when something's happening. Look around the island and go into the library if you've not done so before there's a painting on there that says Tower Rotation.Watch a cutscene where you get informed about something called the Tower Rotation. Put this number into the machine in the chamber by the docks.For people like Zarniwoop who apparently struggle with counting: it's 8. Explore the island and count the Marker Switches.Find and read the super-obvious note, which tells you to count the number of Marker Switches on the island and put it into the machine in the chamber by the docks.Guess it has been a while since I played this, but I have the day off today so. That is the entire Myst experience.ĮDIT: Fuck you, now you made me install realMyst (PROTIP: be sure to run it with Windows XP SP 3 compatibility). But like all puzzles in Myst, if you do not know for sure what to do, you just need to look around more. Or, you do not even have to know the sound clues, and can completely map the area out. ![]() There is only ONE puzzle (yes ONE) that DOES have hints that are only available from another area (they are a sound clue that you can ONLY get from another Age). In fact, if anything, Myst has way too many clues telling you what to do (compared to say Riven, that shit sometimes got RAGE inducing.). Seriously, even the very fist puzzle in the game there is a gigantic hint on a note on what to do, and then there is even more hints that specifically show you what the map markers are, if you aren't sure what those are. Myst Archive - An archive of sites long gone, but not forgotten.Did you even play this game, or are you completely fucking retarded?.Mysterium - annual celebration of all things MYST & D'ni.Guild of Messengers Calendar - Check out what's happening in the community. ![]() Myst Online: Uru Live - Free-to-play multiplayer version of URU!.iTunes - Myst and Riven for iOS Devices.Myst on Wikipediaĭigital versions of every Myst game are finally available for purchase! Myst III Exile and Myst IV Revelation were recently made available on GOG and Steam. Myst is a popular series of graphical adventure games by Cyan Inc. ![]() >!This is a spoiler!< This is a spoiler FAQ Also, please hide any spoilers in your post by using the spoiler tag. If your submission contains any spoilers, please mark your post as containing spoilers (this is available after posting - example). Personal flair editing is also available in the sidebar. Link Flair can be used to better categorize your post. In an effort to keep this subreddit as family-friendly as possible, NSFW material may not be posted. Please keep submissions related to the topic of the Myst games, books, etc. Mods reserve the right to remove posts that ignore this request. Please be civil and respectful to your fellow redditors. This is a pretty open subreddit, and as such, there are very few rules as to what can and cannot be submitted. This is the subreddit for discussion and appreciation of everything Myst, Riven, Exile, Revelation, End of Ages, Uru, and more! Rules ![]()
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Dwarf vs zombies minecraft server list1/15/2024 ![]() ![]() Jesse: Sure, you can get vampires in your Sims, but where else you gonna get Sims in your vampires? V Rising Image credit: Rock Paper Shotgun/Stunlock Studios Developer: Stunlock Studios And if not, there's always the comments to hash it out further.Ģ5. Interestingly, there's quite a bit of crossover between our list and your list below, but the order of them all is very different, which is great! It's always fascinating to see which games resonate with you compared to our own Treehouse tastes, and I hope you all agree among yourselves on the ranking. Besides, we only have 30 games in our own best survival games list, so it seemed like a good place to call it. Plus, things started to get a bit flabby and not very survival-y past the 25 mark point, so we thought it best to cut it off there and stick with the real cream of the crop. Now you may be wondering, hang about, we did 50 games for your favourite strategy list, why only 25 here? Well, the survival genre is something of a more recent phenomenon than strategy games, and most of the votes were accordingly spread across a narrower selection of games. But which game has survived to make it to the top of the pile? Come and find out as we count down your 25 favourite survival games of all time. Your votes have been counted and tallied, and your accompanying words of praise and affection matched accordingly. ![]() ![]() Hot (weeks) off the back of Sons Of The Forest and the Resident Evil 4 remake coming out, we're celebrating your bestest best, most favourite survival games this month. ![]()
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Oil emulsion dressing near me1/15/2024 ![]() Safety Īccording to a 2017 safety review by a scientific panel of the European Food Safety Authority (EFSA), xanthan gum (European food additive number E 415) is extensively digested during intestinal fermentation, and causes no adverse effects, even at high intake amounts. It has slowed tumor growth in mice with skin cancer, stabilized blood sugar, lowered cholesterol and improved the symptoms of dysphagia. Xanthan gum may have some health benefits. Egg white powder (0.2–2.0%) with 0.1–0.4% xanthan gum yields bubbles similar to soap bubbles. Larger amounts result in larger bubbles and denser foam. To make a foam, 0.2–0.8% xanthan gum is typically used. A teaspoon of xanthan gum weighs about 2.5 grams and brings one cup (250 ml) of water to a 1% concentration. Increasing the amount of gum gives a thicker, more stable emulsion up to 1% xanthan gum. An emulsion can be formed with as little as 0.1% (by weight). The greater the ratio of xanthan gum added to a liquid, the thicker the liquid will become. When it exits the bottle, the shear forces are removed and it thickens again, so it clings to the salad. In salad dressing, the addition of xanthan gum makes it thick enough at rest in the bottle to keep the mixture fairly homogeneous, but the shear forces generated by shaking and pouring thins it, so it can be easily poured. When the shear forces are removed, the food will thicken again. This means that a product subjected to shear, whether from mixing, shaking or chewing will thin. This is called shear thinning or pseudoplasticity. The viscosity of xanthan gum solutions decreases with higher shear rates. Furthermore, thiolated xanthan gum (see thiomers) has shown potential for drug delivery, since by the covalent attachment of thiol groups to this polysaccharide high mucoadhesive and permeation enhancing properties can be introduced. Xanthan gum is under preliminary research for its potential uses in tissue engineering to construct hydrogels and scaffolds supporting three-dimensional tissue formation. It is also used in oil-in-water emulsions to enhance droplet coalescence. In cosmetics, xanthan gum is used to prepare water gels. It has been added to concrete poured underwater, to increase its viscosity and prevent washout. The widespread use of horizontal drilling and the demand for good control of drilled solids has led to its expanded use. When circulation stops, the solids remain suspended in the drilling fluid. Xanthan gum provides great "low end" rheology. ![]() These fluids carry the solids cut by the drilling bit to the surface. In the oil industry, xanthan gum is used in large quantities to thicken drilling mud. Xanthan gum is used in a wide range of food products, such as sauces, dressings, meat and poultry products, bakery products, confectionery products, beverages, dairy products, and others. ![]() In most foods it is used at concentrations of 0.5% or less. In gluten-free baking, xanthan gum is used to give the dough or batter the stickiness that would otherwise be achieved with gluten. It is also a preferred method of thickening liquids for those with swallowing disorders, since it does not change the color or flavor of foods or beverages at typical use levels. Xanthan gum also helps thicken commercial egg substitutes made from egg whites, to replace the fat and emulsifiers found in yolks. Toothpaste often contains xanthan gum as a binder to keep the product uniform. Xanthan gum helps create the desired texture in many ice creams. Xanthan gum also helps suspend solid particles, such as spices. It helps to prevent oil separation by stabilizing the emulsion, although it is not an emulsifier. In foods, xanthan gum is common in salad dressings and sauces. Xanthan gum, 1%, can produce a significant increase in the viscosity of a liquid. Xanthan gum derives its name from the species of bacteria used during the fermentation process, Xanthomonas campestris. It was approved for use in foods in 1968 and is accepted as a safe food additive in the US, Canada, European countries, and many other countries, with E number E415, and CAS number 1. ![]() Xanthan gum was discovered by Allene Rosalind Jeanes and her research team at the United States Department of Agriculture, and brought into commercial production by CP Kelco under the trade name Kelzan in the early 1960s. It can be produced from simple sugars using a fermentation process and derives its name from the species of bacteria used, Xanthomonas campestris. It is an effective thickening agent, emulsifier, and stabilizer that prevents ingredients from separating. Xanthan gum ( / ˈ z æ n θ ə n/) is a polysaccharide with many industrial uses, including as a common food additive. ![]()
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Selfie photo caption1/15/2024 ![]() ![]() Most importantly on weekend we also spend more time than usual on social media not all of us but most of us, yeah we don’t have to debate about social media good or bad, here you come for weekend Instagram captions. Whatsoever, working 9 to 5 or doing business that takes effort hard work, and consistency as humans on need at least some time to relax and most of US cannot afford a leave of a week or 2 every month but still, we have weekends we can when we can enjoy with ourselves doing party e all over the club hanging out Netflix and chill, and just read a book as per your preference. Working all over the week starting from Monday and waiting for the Friday night that most people do, we all love weekends not out accept some legends who will be like Elon Musk. Weekend Instagram Captions For Photos/Pictures.Don’t be afraid to get creative with your captions. Getting in the habit of crafting a caption is important because it sets the tone for your photo. With witty Instagram captions for selfies, you can charm your followers with your witty presence. Keeping my standards as high as my heels. ![]() Embracing the glorious mess that is me.Life is better when you’re laughing with friends.Don’t ever let anyone make you feel like you’re nobody.A pizza and your opinion are different because I only asked for pizza.You’ll hear me not caring if you listen closely.Classy, never trashy, and a little bit sassy.Smile every day while you still have teeth. I heard you wish I took a selfie today.I followed my dreams, and it led me to the mall.This is the most magical photo you’ll ever see today.If I were funny, I would have a better Instagram caption.A little lipstick and a lot of confidence.You may regret some things, but you’ll never regret being kind.70+ Clever and Witty Instagram Captions for Selfies It has been proven that posts with captions perform exceedingly well on social media than those without. Not only does it give more context to your post, but it also helps you tell a story differently. With a good caption on your post, you can make a simple photo really stand out. And this worldwide phenomenon is not going anywhere anytime soon. Taking selfies has never been easier, thanks to the front cameras on our phones. You can stay connected with friends you haven’t seen in a long time just by sharing selfies. Selfies are also a great way to connect with people who you don’t get a chance to see face-to-face often. One of which is because taking a selfie allows us to express our creativity. A lot of people LOVE taking selfies for a lot of reasons. Photo by Taan Huyn on Unsplash What Makes Selfies so Popular?Įverybody’s doing it, from celebrities even to politicians. This article will also cover the importance of captions and how they can impact your Instagram presence. You’re sure to pick something that will perfectly fit your photo, from cheeky captions to clever and creative quotes. Check out the 70+ witty Instagram captions for selfies we’ve listed in this article. And it deserves an awesome caption to go along with it! If you’re out of ideas for a good caption, we’ve got your back. That cute selfie deserves a spot on your Instagram feed. ![]()
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Molecular orbital theory diagram1/15/2024 ![]() Compare the bond order to that seen in the Lewis structure (remember that an electron in an antibonding orbital cancels the stabilization due to bonding of an electron in a bonding orbital). Bonding between atoms occurs when they come into close enough proximity for their orbitals to overlap. Construct a qualitative molecular orbital diagram for chlorine, Cl 2. To further demonstrate the consistency of the. The work also gives a clear definition of the terms bonding, non-bonding and antibonding molecular orbitals. Molecular Orbital Theory - The goal of molecular orbital theory is to describe molecules in a similar way to how we describe atoms, that is, in terms of orbitals, orbital diagrams, and electron configurations. The orbital correlation diagram in predicts the same thing-two electrons fill a single bonding molecular orbital. Walsh's original diagrams seem to be based on an unusual type of delocalized molecular orbital. If these distinctions are not made, one may emerge with a diagram which is a mixture of several different but related diagrams. Molecular orbital diagram is a qualitative descriptive tool explaining chemical bonding in molecules in terms of molecular orbital theory in general and the. ![]() The atomic orbitals combine to produce the following molecular orbital diagram: Here the 2p g orbital is occupied by two electrons to give a total bond order of three. The general method is to reduce the self-consistent field molecular orbital theory to the independent electron theory by systematic approximations and by appeal to physical arguments.īroadly speaking, the results support Walsh's method of constructing his diagrams but they also show that it is important to distinguish clearly between ionization energies and binding energies and also between the different types of delocalized molecular orbital. Pauling with others, developed Resonance Theory, which provided the rationale to an all-embracing orbital theory. This interpretation is discussed in the context of the Walsh diagram for the water molecule. ![]() It is suggested that the “one electron energy” or “binding energy” of the independent electron molecular orbital theory is the change in the ionization energy of the molecular orbital on molecule formation. ![]() |